A new synthetic procedure for the preparation of pyridinium tetrafluoroborate and hexafluorosilicate
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2021, Journal of Organic ChemistryAmmonium hexafluoridosilicates: Synthesis, structures, properties, applications
2019, Journal of Fluorine ChemistryCitation Excerpt :The vibrational spectra of the hexafluoridosilicate anion (Oh symmetry) are characterized by the presence of two vibrations active in the IR spectra, and three vibrations active in the Raman spectra [123]. Oscillations ν(SiF) and δ(SiF2) (F1u) are detected in the IR spectra of hexafluoridosilicates in the form of absorption bands around 730 and 470 cm–1 [19,21–23,27–29,32,34,36–38,40–44]. In turn, vibrations ν(SiF) (A1g), ν(SiF) (Eg) and δ(SiF2) (F2g) are recorded in the Raman spectra around 660, 470 and 400 cm–1 [28,45,61,62].
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